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Novel cycloaurated gold(III) complexes and their effects on styrene polymerization

Hanhan, Murat Emre


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  "@context": "https://schema.org/", 
  "@id": 20519, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Hanhan, Murat Emre"
    }
  ], 
  "datePublished": "2011-01-01", 
  "description": "Novel cycloaurated gold(III) complexes were prepared by using Schiff bases with different substituents. Effects of the synthesized gold(III) complexes and substituent groups on styrene polymerization were investigated. As a result of these investigations, it was observed that gold(III) complexes could not catalyze polymerization reaction without addition of a co-catalyst like NaBAr'(4) (Ar'=3,5-bis(trifluoromethyl) phenyl). All ligands and complexes were characterized by using H-1 nuclear magnetic resonance (NMR), C-13-NMR, LC-MS, elemental analysis and FT-IR techniques. The architecture of the polymer was determined as an atactic or sydiotactic polymer by using C-13-NMR and DSC techniques. Molecular weights of the polymers were analyzed by using gel permeation chromatogram (GPC).", 
  "headline": "Novel cycloaurated gold(III) complexes and their effects on styrene polymerization", 
  "identifier": 20519, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Novel cycloaurated gold(III) complexes and their effects on styrene polymerization", 
  "url": "https://aperta.ulakbim.gov.tr/record/20519"
}
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