1 Ocak 2011 Dergi makalesi Açık Erişim

Kara, Hulya; Adams, Christopher J.; Schwarz, Bjoern; Orpen, A. Guy

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  <dc:creator>Kara, Hulya</dc:creator>
  <dc:creator>Adams, Christopher J.</dc:creator>
  <dc:creator>Schwarz, Bjoern</dc:creator>
  <dc:creator>Orpen, A. Guy</dc:creator>
  <dc:date>2011-01-01</dc:date>
  <dc:description>A series of crystalline salts based on the complex dianion [Fe(dto)(2)(NO)](2-) (dto = 1,2-dithiooxalate) with hydrogen-bond donor cations have been synthesised. The preparation and structural characterisation of the new crystalline phases [4,4'-H(2)bipy][Fe(dto)(2)(NO)]center dot H2O (1), [3,3'-H(2)bipy][Fe (dto)(2)(NO)] (2) and [H(2)Me(4)bipyz][Fe(dto)(2)(NO)]center dot 2H(2)O (3) (Me(4)bipyz = 3,3',5,5'-tetramethyl-4,4'-bipyrazole) are reported, and show that a charge-assisted NH center dot center dot center dot dto synthon is formed in each of compounds 1-3. In compound 1 the anion forms a dimer in the solid-state, and variable temperature magnetic susceptibility measurements reveal a weak antiferromagnetic interaction with a best fit superexchange parameter J = -3.18 (2) cm(-1), where H = -2JS(1)S(2).</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/18337</dc:identifier>
  <dc:identifier>oai:zenodo.org:18337</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>CRYSTENGCOMM 13(16) 5082-5087</dc:source>
  <dc:title>The use of [Fe(dithiooxalate)(2)(NO)](2-) as a tecton in crystal engineering</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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