1 Ocak 2011 Dergi makalesi Açık Erişim

Kara, Hulya; Adams, Christopher J.; Schwarz, Bjoern; Orpen, A. Guy

DataCite XML

<?xml version='1.0' encoding='utf-8'?>
<resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd">
  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/18337</identifier>
  <creators>
    <creator>
      <creatorName>Kara, Hulya</creatorName>
      <givenName>Hulya</givenName>
      <familyName>Kara</familyName>
    </creator>
    <creator>
      <creatorName>Adams, Christopher J.</creatorName>
      <givenName>Christopher J.</givenName>
      <familyName>Adams</familyName>
      <affiliation>Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England</affiliation>
    </creator>
    <creator>
      <creatorName>Schwarz, Bjoern</creatorName>
      <givenName>Bjoern</givenName>
      <familyName>Schwarz</familyName>
      <affiliation>IFW Dresden, Inst Complex Mat, D-01069 Dresden, Germany</affiliation>
    </creator>
    <creator>
      <creatorName>Orpen, A. Guy</creatorName>
      <givenName>A. Guy</givenName>
      <familyName>Orpen</familyName>
      <affiliation>Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England</affiliation>
    </creator>
  </creators>
  <titles>
    <title>The Use Of [Fe(Dithiooxalate)(2)(No)](2-) As A Tecton In Crystal Engineering</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2011</publicationYear>
  <dates>
    <date dateType="Issued">2011-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/18337</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1039/c1ce05309d</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A series of crystalline salts based on the complex dianion [Fe(dto)(2)(NO)](2-) (dto = 1,2-dithiooxalate) with hydrogen-bond donor cations have been synthesised. The preparation and structural characterisation of the new crystalline phases [4,4'-H(2)bipy][Fe(dto)(2)(NO)]center dot H2O (1), [3,3'-H(2)bipy][Fe (dto)(2)(NO)] (2) and [H(2)Me(4)bipyz][Fe(dto)(2)(NO)]center dot 2H(2)O (3) (Me(4)bipyz = 3,3',5,5'-tetramethyl-4,4'-bipyrazole) are reported, and show that a charge-assisted NH center dot center dot center dot dto synthon is formed in each of compounds 1-3. In compound 1 the anion forms a dimer in the solid-state, and variable temperature magnetic susceptibility measurements reveal a weak antiferromagnetic interaction with a best fit superexchange parameter J = -3.18 (2) cm(-1), where H = -2JS(1)S(2).</description>
  </descriptions>
</resource>