1 Ocak 2011 Dergi makalesi Açık Erişim

Kara, Hulya; Adams, Christopher J.; Schwarz, Bjoern; Orpen, A. Guy

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  "@id": 18337, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Kara, Hulya"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England", 
      "name": "Adams, Christopher J."
    }, 
    {
      "@type": "Person", 
      "affiliation": "IFW Dresden, Inst Complex Mat, D-01069 Dresden, Germany", 
      "name": "Schwarz, Bjoern"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England", 
      "name": "Orpen, A. Guy"
    }
  ], 
  "datePublished": "2011-01-01", 
  "description": "A series of crystalline salts based on the complex dianion [Fe(dto)(2)(NO)](2-) (dto = 1,2-dithiooxalate) with hydrogen-bond donor cations have been synthesised. The preparation and structural characterisation of the new crystalline phases [4,4'-H(2)bipy][Fe(dto)(2)(NO)]center dot H2O (1), [3,3'-H(2)bipy][Fe (dto)(2)(NO)] (2) and [H(2)Me(4)bipyz][Fe(dto)(2)(NO)]center dot 2H(2)O (3) (Me(4)bipyz = 3,3',5,5'-tetramethyl-4,4'-bipyrazole) are reported, and show that a charge-assisted NH center dot center dot center dot dto synthon is formed in each of compounds 1-3. In compound 1 the anion forms a dimer in the solid-state, and variable temperature magnetic susceptibility measurements reveal a weak antiferromagnetic interaction with a best fit superexchange parameter J = -3.18 (2) cm(-1), where H = -2JS(1)S(2).", 
  "headline": "The use of [Fe(dithiooxalate)(2)(NO)](2-) as a tecton in crystal engineering", 
  "identifier": 18337, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "The use of [Fe(dithiooxalate)(2)(NO)](2-) as a tecton in crystal engineering", 
  "url": "https://aperta.ulakbim.gov.tr/record/18337"
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