1 Ocak 2011 Dergi makalesi Açık Erişim

Kara, Hulya; Adams, Christopher J.; Schwarz, Bjoern; Orpen, A. Guy

Citation Style Language JSON

{
  "DOI": "10.1039/c1ce05309d", 
  "abstract": "A series of crystalline salts based on the complex dianion [Fe(dto)(2)(NO)](2-) (dto = 1,2-dithiooxalate) with hydrogen-bond donor cations have been synthesised. The preparation and structural characterisation of the new crystalline phases [4,4'-H(2)bipy][Fe(dto)(2)(NO)]center dot H2O (1), [3,3'-H(2)bipy][Fe (dto)(2)(NO)] (2) and [H(2)Me(4)bipyz][Fe(dto)(2)(NO)]center dot 2H(2)O (3) (Me(4)bipyz = 3,3',5,5'-tetramethyl-4,4'-bipyrazole) are reported, and show that a charge-assisted NH center dot center dot center dot dto synthon is formed in each of compounds 1-3. In compound 1 the anion forms a dimer in the solid-state, and variable temperature magnetic susceptibility measurements reveal a weak antiferromagnetic interaction with a best fit superexchange parameter J = -3.18 (2) cm(-1), where H = -2JS(1)S(2).", 
  "author": [
    {
      "family": "Kara", 
      "given": " Hulya"
    }, 
    {
      "family": "Adams", 
      "given": " Christopher J."
    }, 
    {
      "family": "Schwarz", 
      "given": " Bjoern"
    }, 
    {
      "family": "Orpen", 
      "given": " A. Guy"
    }
  ], 
  "container_title": "CRYSTENGCOMM", 
  "id": "18337", 
  "issue": "16", 
  "issued": {
    "date-parts": [
      [
        2011, 
        1, 
        1
      ]
    ]
  }, 
  "page": "5082-5087", 
  "title": "The use of [Fe(dithiooxalate)(2)(NO)](2-) as a tecton in crystal engineering", 
  "type": "article-journal", 
  "volume": "13"
}