Dergi makalesi Açık Erişim
Kilic, Ahmet; Palali, Ahmet Arif; Durgun, Mustafa; Tasci, Zeynep; Ulusoy, Mahmut
<?xml version='1.0' encoding='UTF-8'?> <record xmlns="http://www.loc.gov/MARC21/slim"> <leader>00000nam##2200000uu#4500</leader> <datafield tag="245" ind1=" " ind2=" "> <subfield code="a">The coupling of carbon dioxide and epoxides by phenanthroline derivatives containing different Cu(II) complexes as catalyst</subfield> </datafield> <datafield tag="909" ind1="C" ind2="4"> <subfield code="p">SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY</subfield> <subfield code="v">113</subfield> <subfield code="c">432-438</subfield> </datafield> <controlfield tag="001">16995</controlfield> <datafield tag="980" ind1=" " ind2=" "> <subfield code="a">user-tubitak-destekli-proje-yayinlari</subfield> </datafield> <datafield tag="520" ind1=" " ind2=" "> <subfield code="a">A series of the mononuclear Cu(II) metal complexes containing the ligand Bdppz [(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)-phenyl-methanone] (L-1) and Aqphen [(12,17-dihydronaphthol[2,3-h]dipyrido[3,2-a:2',3'-c]-phenazine-12,17-dione)] (L-2) were synthesized and used as catalyst for the coupling of carbon dioxide (CO2) and liquid epoxide which served as both reactant and solvent. Dimethylamino pyridine (DMAP) was used as co-catalyst. The yields of epoxides to corresponding cyclic carbonates were determined by comparing the ratio of product to substrate in the H-1 NMR spectrum of an aliquot of the reaction mixture. The mononuclear Cu(II) complexes of these ligands were synthesized by treating an ethanol solvent of the appropriate ligand with a different molar amount of CuCl2 center dot 2H(2)O. The Cu(II) complexes were characterized by FT-IR, UV-Vis, elemental analysis, melting point analysis, mass spectra, molar conductivity measurements and magnetic susceptibility techniques. The reaction of the Bdppz and Aqphen ligands in a 1:1, 1:2 or 1:3 mole ratio with CuCl2 center dot 2H(2)O afforded ionic Cu(II) complexes in the presence of Et3N. (C) 2013 Elsevier B.V. All rights reserved.</subfield> </datafield> <datafield tag="650" ind1="1" ind2="7"> <subfield code="2">opendefinition.org</subfield> <subfield code="a">cc-by</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="u">Univ Harran, Dept Chem, Sanliurfa, Turkey</subfield> <subfield code="a">Palali, Ahmet Arif</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="u">Univ Harran, Dept Chem, Sanliurfa, Turkey</subfield> <subfield code="a">Durgun, Mustafa</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="u">Univ Mugla, Dept Chem, TR-4800 Mugla, Turkey</subfield> <subfield code="a">Tasci, Zeynep</subfield> </datafield> <datafield tag="700" ind1=" " ind2=" "> <subfield code="u">Univ Harran, Dept Chem, Sanliurfa, Turkey</subfield> <subfield code="a">Ulusoy, Mahmut</subfield> </datafield> <datafield tag="980" ind1=" " ind2=" "> <subfield code="b">article</subfield> <subfield code="a">publication</subfield> </datafield> <datafield tag="542" ind1=" " ind2=" "> <subfield code="l">open</subfield> </datafield> <datafield tag="100" ind1=" " ind2=" "> <subfield code="u">Univ Harran, Dept Chem, Sanliurfa, Turkey</subfield> <subfield code="a">Kilic, Ahmet</subfield> </datafield> <datafield tag="260" ind1=" " ind2=" "> <subfield code="c">2013-01-01</subfield> </datafield> <controlfield tag="005">20210315094848.0</controlfield> <datafield tag="909" ind1="C" ind2="O"> <subfield code="o">oai:zenodo.org:16995</subfield> <subfield code="p">user-tubitak-destekli-proje-yayinlari</subfield> </datafield> <datafield tag="856" ind1="4" ind2=" "> <subfield code="z">md5:6f987912ddaec8d4f026b6ef08d06f39</subfield> <subfield code="s">278</subfield> <subfield code="u">https://aperta.ulakbim.gov.trrecord/16995/files/bib-9d9bd9fe-4588-41cc-bb5a-777a3fd2ac9a.txt</subfield> </datafield> <datafield tag="540" ind1=" " ind2=" "> <subfield code="u">http://www.opendefinition.org/licenses/cc-by</subfield> <subfield code="a">Creative Commons Attribution</subfield> </datafield> <datafield tag="024" ind1=" " ind2=" "> <subfield code="a">10.1016/j.saa.2013.04.124</subfield> <subfield code="2">doi</subfield> </datafield> </record>
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