1 Ocak 2013 Dergi makalesi Açık Erişim

Kilic, Ahmet; Palali, Ahmet Arif; Durgun, Mustafa; Tasci, Zeynep; Ulusoy, Mahmut

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{
  "@context": "https://schema.org/", 
  "@id": 16995, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Univ Harran, Dept Chem, Sanliurfa, Turkey", 
      "name": "Kilic, Ahmet"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Harran, Dept Chem, Sanliurfa, Turkey", 
      "name": "Palali, Ahmet Arif"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Harran, Dept Chem, Sanliurfa, Turkey", 
      "name": "Durgun, Mustafa"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Mugla, Dept Chem, TR-4800 Mugla, Turkey", 
      "name": "Tasci, Zeynep"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Univ Harran, Dept Chem, Sanliurfa, Turkey", 
      "name": "Ulusoy, Mahmut"
    }
  ], 
  "datePublished": "2013-01-01", 
  "description": "A series of the mononuclear Cu(II) metal complexes containing the ligand Bdppz [(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)-phenyl-methanone] (L-1) and Aqphen [(12,17-dihydronaphthol[2,3-h]dipyrido[3,2-a:2',3'-c]-phenazine-12,17-dione)] (L-2) were synthesized and used as catalyst for the coupling of carbon dioxide (CO2) and liquid epoxide which served as both reactant and solvent. Dimethylamino pyridine (DMAP) was used as co-catalyst. The yields of epoxides to corresponding cyclic carbonates were determined by comparing the ratio of product to substrate in the H-1 NMR spectrum of an aliquot of the reaction mixture. The mononuclear Cu(II) complexes of these ligands were synthesized by treating an ethanol solvent of the appropriate ligand with a different molar amount of CuCl2 center dot 2H(2)O. The Cu(II) complexes were characterized by FT-IR, UV-Vis, elemental analysis, melting point analysis, mass spectra, molar conductivity measurements and magnetic susceptibility techniques. The reaction of the Bdppz and Aqphen ligands in a 1:1, 1:2 or 1:3 mole ratio with CuCl2 center dot 2H(2)O afforded ionic Cu(II) complexes in the presence of Et3N. (C) 2013 Elsevier B.V. All rights reserved.", 
  "headline": "The coupling of carbon dioxide and epoxides by phenanthroline derivatives containing different Cu(II) complexes as catalyst", 
  "identifier": 16995, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "The coupling of carbon dioxide and epoxides by phenanthroline derivatives containing different Cu(II) complexes as catalyst", 
  "url": "https://aperta.ulakbim.gov.tr/record/16995"
}