1 Ocak 2013 Dergi makalesi Açık Erişim

Kilic, Ahmet; Palali, Ahmet Arif; Durgun, Mustafa; Tasci, Zeynep; Ulusoy, Mahmut

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/16995</identifier>
  <creators>
    <creator>
      <creatorName>Kilic, Ahmet</creatorName>
      <givenName>Ahmet</givenName>
      <familyName>Kilic</familyName>
      <affiliation>Univ Harran, Dept Chem, Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Palali, Ahmet Arif</creatorName>
      <givenName>Ahmet Arif</givenName>
      <familyName>Palali</familyName>
      <affiliation>Univ Harran, Dept Chem, Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Durgun, Mustafa</creatorName>
      <givenName>Mustafa</givenName>
      <familyName>Durgun</familyName>
      <affiliation>Univ Harran, Dept Chem, Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tasci, Zeynep</creatorName>
      <givenName>Zeynep</givenName>
      <familyName>Tasci</familyName>
      <affiliation>Univ Mugla, Dept Chem, TR-4800 Mugla, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ulusoy, Mahmut</creatorName>
      <givenName>Mahmut</givenName>
      <familyName>Ulusoy</familyName>
      <affiliation>Univ Harran, Dept Chem, Sanliurfa, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>The Coupling Of Carbon Dioxide And Epoxides By Phenanthroline Derivatives Containing Different Cu(Ii) Complexes As Catalyst</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/16995</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.saa.2013.04.124</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A series of the mononuclear Cu(II) metal complexes containing the ligand Bdppz [(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)-phenyl-methanone] (L-1) and Aqphen [(12,17-dihydronaphthol[2,3-h]dipyrido[3,2-a:2',3'-c]-phenazine-12,17-dione)] (L-2) were synthesized and used as catalyst for the coupling of carbon dioxide (CO2) and liquid epoxide which served as both reactant and solvent. Dimethylamino pyridine (DMAP) was used as co-catalyst. The yields of epoxides to corresponding cyclic carbonates were determined by comparing the ratio of product to substrate in the H-1 NMR spectrum of an aliquot of the reaction mixture. The mononuclear Cu(II) complexes of these ligands were synthesized by treating an ethanol solvent of the appropriate ligand with a different molar amount of CuCl2 center dot 2H(2)O. The Cu(II) complexes were characterized by FT-IR, UV-Vis, elemental analysis, melting point analysis, mass spectra, molar conductivity measurements and magnetic susceptibility techniques. The reaction of the Bdppz and Aqphen ligands in a 1:1, 1:2 or 1:3 mole ratio with CuCl2 center dot 2H(2)O afforded ionic Cu(II) complexes in the presence of Et3N. (C) 2013 Elsevier B.V. All rights reserved.</description>
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