Dergi makalesi Açık Erişim
Kilic, Ahmet; Palali, Ahmet Arif; Durgun, Mustafa; Tasci, Zeynep; Ulusoy, Mahmut
A series of the mononuclear Cu(II) metal complexes containing the ligand Bdppz [(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)-phenyl-methanone] (L-1) and Aqphen [(12,17-dihydronaphthol[2,3-h]dipyrido[3,2-a:2',3'-c]-phenazine-12,17-dione)] (L-2) were synthesized and used as catalyst for the coupling of carbon dioxide (CO2) and liquid epoxide which served as both reactant and solvent. Dimethylamino pyridine (DMAP) was used as co-catalyst. The yields of epoxides to corresponding cyclic carbonates were determined by comparing the ratio of product to substrate in the H-1 NMR spectrum of an aliquot of the reaction mixture. The mononuclear Cu(II) complexes of these ligands were synthesized by treating an ethanol solvent of the appropriate ligand with a different molar amount of CuCl2 center dot 2H(2)O. The Cu(II) complexes were characterized by FT-IR, UV-Vis, elemental analysis, melting point analysis, mass spectra, molar conductivity measurements and magnetic susceptibility techniques. The reaction of the Bdppz and Aqphen ligands in a 1:1, 1:2 or 1:3 mole ratio with CuCl2 center dot 2H(2)O afforded ionic Cu(II) complexes in the presence of Et3N. (C) 2013 Elsevier B.V. All rights reserved.
Dosya adı | Boyutu | |
---|---|---|
bib-9d9bd9fe-4588-41cc-bb5a-777a3fd2ac9a.txt
md5:6f987912ddaec8d4f026b6ef08d06f39 |
278 Bytes | İndir |
Görüntülenme | 22 |
İndirme | 4 |
Veri hacmi | 1.1 kB |
Tekil görüntülenme | 21 |
Tekil indirme | 4 |