1 Ocak 2013 Dergi makalesi Açık Erişim

Kilic, Ahmet; Palali, Ahmet Arif; Durgun, Mustafa; Tasci, Zeynep; Ulusoy, Mahmut; Dagdevren, Metin; Yilmaz, Ismail

Dublin Core

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  <dc:creator>Kilic, Ahmet</dc:creator>
  <dc:creator>Palali, Ahmet Arif</dc:creator>
  <dc:creator>Durgun, Mustafa</dc:creator>
  <dc:creator>Tasci, Zeynep</dc:creator>
  <dc:creator>Ulusoy, Mahmut</dc:creator>
  <dc:creator>Dagdevren, Metin</dc:creator>
  <dc:creator>Yilmaz, Ismail</dc:creator>
  <dc:date>2013-01-01</dc:date>
  <dc:description>Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by H-1 and C-13 NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)(2)] complex (2). Then, the intramolecular O-H center dot center dot center dot O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)(2)Cu-2(N-N)(2)](ClO4)(2) oxime complexes (3-7) where N-N = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3'-dicarboxy-2,2'-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime)(2)] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes. (C) 2012 Elsevier B. V. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/15109</dc:identifier>
  <dc:identifier>oai:zenodo.org:15109</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>INORGANICA CHIMICA ACTA 394 635-644</dc:source>
  <dc:title>Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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