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Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst

Kilic, Ahmet; Palali, Ahmet Arif; Durgun, Mustafa; Tasci, Zeynep; Ulusoy, Mahmut; Dagdevren, Metin; Yilmaz, Ismail


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{
  "@context": "https://schema.org/", 
  "@id": 15109, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Harran Univ, Dept Chem, Sanliurfa, Turkey", 
      "name": "Kilic, Ahmet"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Harran Univ, Dept Chem, Sanliurfa, Turkey", 
      "name": "Palali, Ahmet Arif"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Harran Univ, Dept Chem, Sanliurfa, Turkey", 
      "name": "Durgun, Mustafa"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Mugla Univ, Dept Chem, TR-48000 Kotekli, Mugla, Turkey", 
      "name": "Tasci, Zeynep"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Harran Univ, Dept Chem, Sanliurfa, Turkey", 
      "name": "Ulusoy, Mahmut"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Dagdevren, Metin"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Yilmaz, Ismail"
    }
  ], 
  "datePublished": "2013-01-01", 
  "description": "Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by H-1 and C-13 NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)(2)] complex (2). Then, the intramolecular O-H center dot center dot center dot O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)(2)Cu-2(N-N)(2)](ClO4)(2) oxime complexes (3-7) where N-N = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3'-dicarboxy-2,2'-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime)(2)] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes. (C) 2012 Elsevier B. V. All rights reserved.", 
  "headline": "Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst", 
  "identifier": 15109, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst", 
  "url": "https://aperta.ulakbim.gov.tr/record/15109"
}
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