1 Ocak 2013 Dergi makalesi Açık Erişim

Kilic, Ahmet; Palali, Ahmet Arif; Durgun, Mustafa; Tasci, Zeynep; Ulusoy, Mahmut; Dagdevren, Metin; Yilmaz, Ismail

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/15109</identifier>
  <creators>
    <creator>
      <creatorName>Kilic, Ahmet</creatorName>
      <givenName>Ahmet</givenName>
      <familyName>Kilic</familyName>
      <affiliation>Harran Univ, Dept Chem, Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Palali, Ahmet Arif</creatorName>
      <givenName>Ahmet Arif</givenName>
      <familyName>Palali</familyName>
      <affiliation>Harran Univ, Dept Chem, Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Durgun, Mustafa</creatorName>
      <givenName>Mustafa</givenName>
      <familyName>Durgun</familyName>
      <affiliation>Harran Univ, Dept Chem, Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Tasci, Zeynep</creatorName>
      <givenName>Zeynep</givenName>
      <familyName>Tasci</familyName>
      <affiliation>Mugla Univ, Dept Chem, TR-48000 Kotekli, Mugla, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ulusoy, Mahmut</creatorName>
      <givenName>Mahmut</givenName>
      <familyName>Ulusoy</familyName>
      <affiliation>Harran Univ, Dept Chem, Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Dagdevren, Metin</creatorName>
      <givenName>Metin</givenName>
      <familyName>Dagdevren</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yilmaz, Ismail</creatorName>
      <givenName>Ismail</givenName>
      <familyName>Yilmaz</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis, Characterization, Electrochemical Properties And Conversions Of Carbon Dioxide To Cyclic Carbonates Mononuclear And Multinuclear Oxime Complexes Using As Catalyst</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/15109</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.ica.2012.09.020</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by H-1 and C-13 NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)(2)] complex (2). Then, the intramolecular O-H center dot center dot center dot O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)(2)Cu-2(N-N)(2)](ClO4)(2) oxime complexes (3-7) where N-N = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3'-dicarboxy-2,2'-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime)(2)] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes. (C) 2012 Elsevier B. V. All rights reserved.</description>
  </descriptions>
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