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Poly(styrene peroxide) and poly(methyl methacrylate peroxide) for grafting on unsaturated bacterial polyesters

Cakmakli, B; Hazer, B; Borcakli, M


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  "@context": "https://schema.org/", 
  "@id": 95481, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Cakmakli, B"
    }, 
    {
      "@type": "Person", 
      "name": "Hazer, B"
    }, 
    {
      "@type": "Person", 
      "name": "Borcakli, M"
    }
  ], 
  "datePublished": "2001-01-01", 
  "description": "A new soluble terephthaloyl oligoperoxide (OTP) was synthesized by the reaction of terephthaloyl peroxide and 2.5-dimethyl 2,5-dihydroperoxy hexane. Thermal polymerization of vinyl monomers (styrene, methyl methacrylate) with OTP yielded poly(styrene peroxide) (PS-P) and poly(methyl methacrylate peroxide) (PMMA-P) which are used in the grafting reactions onto medium chain length unsaturated bacterial polyester obtained from soybean oily acids with Pseudomonas oleovorans poly(3-hydroxy alkanoate), (PHA). PS-g-PHA and PMMA-g-PHA graft copolymers isolated from related homopolymers were characterizated by H-1 NMR spectrometry, FT-IR spectroscopy, thermal analysis and gel permeation chromatographic (GPC) techniques. Swelling measurement of the crosslink-ed graft copolymers were also measured to calculate q(v) values.", 
  "headline": "Poly(styrene peroxide) and poly(methyl methacrylate peroxide) for grafting on unsaturated bacterial polyesters", 
  "identifier": 95481, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Poly(styrene peroxide) and poly(methyl methacrylate peroxide) for grafting on unsaturated bacterial polyesters", 
  "url": "https://aperta.ulakbim.gov.tr/record/95481"
}
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