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Poly(styrene peroxide) and poly(methyl methacrylate peroxide) for grafting on unsaturated bacterial polyesters

Cakmakli, B; Hazer, B; Borcakli, M


DataCite XML

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/95481</identifier>
  <creators>
    <creator>
      <creatorName>Cakmakli, B</creatorName>
      <givenName>B</givenName>
      <familyName>Cakmakli</familyName>
    </creator>
    <creator>
      <creatorName>Hazer, B</creatorName>
      <givenName>B</givenName>
      <familyName>Hazer</familyName>
    </creator>
    <creator>
      <creatorName>Borcakli, M</creatorName>
      <givenName>M</givenName>
      <familyName>Borcakli</familyName>
    </creator>
  </creators>
  <titles>
    <title>Poly(Styrene Peroxide) And Poly(Methyl Methacrylate Peroxide) For Grafting On Unsaturated Bacterial Polyesters</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2001</publicationYear>
  <dates>
    <date dateType="Issued">2001-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/95481</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.81043/aperta.95480</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.81043/aperta.95481</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A new soluble terephthaloyl oligoperoxide (OTP) was synthesized by the reaction of terephthaloyl peroxide and 2.5-dimethyl 2,5-dihydroperoxy hexane. Thermal polymerization of vinyl monomers (styrene, methyl methacrylate) with OTP yielded poly(styrene peroxide) (PS-P) and poly(methyl methacrylate peroxide) (PMMA-P) which are used in the grafting reactions onto medium chain length unsaturated bacterial polyester obtained from soybean oily acids with Pseudomonas oleovorans poly(3-hydroxy alkanoate), (PHA). PS-g-PHA and PMMA-g-PHA graft copolymers isolated from related homopolymers were characterizated by H-1 NMR spectrometry, FT-IR spectroscopy, thermal analysis and gel permeation chromatographic (GPC) techniques. Swelling measurement of the crosslink-ed graft copolymers were also measured to calculate q(v) values.</description>
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