Dergi makalesi Açık Erişim
Cakmakli, B; Hazer, B; Borcakli, M
{ "URL": "https://aperta.ulakbim.gov.tr/record/95481", "abstract": "A new soluble terephthaloyl oligoperoxide (OTP) was synthesized by the reaction of terephthaloyl peroxide and 2.5-dimethyl 2,5-dihydroperoxy hexane. Thermal polymerization of vinyl monomers (styrene, methyl methacrylate) with OTP yielded poly(styrene peroxide) (PS-P) and poly(methyl methacrylate peroxide) (PMMA-P) which are used in the grafting reactions onto medium chain length unsaturated bacterial polyester obtained from soybean oily acids with Pseudomonas oleovorans poly(3-hydroxy alkanoate), (PHA). PS-g-PHA and PMMA-g-PHA graft copolymers isolated from related homopolymers were characterizated by H-1 NMR spectrometry, FT-IR spectroscopy, thermal analysis and gel permeation chromatographic (GPC) techniques. Swelling measurement of the crosslink-ed graft copolymers were also measured to calculate q(v) values.", "author": [ { "family": "Cakmakli", "given": " B" }, { "family": "Hazer", "given": " B" }, { "family": "Borcakli", "given": " M" } ], "container_title": "MACROMOLECULAR BIOSCIENCE", "id": "95481", "issue": "8", "issued": { "date-parts": [ [ 2001, 1, 1 ] ] }, "page": "348-354", "title": "Poly(styrene peroxide) and poly(methyl methacrylate peroxide) for grafting on unsaturated bacterial polyesters", "type": "article-journal", "volume": "1" }
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