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Poly(styrene peroxide) and poly(methyl methacrylate peroxide) for grafting on unsaturated bacterial polyesters

Cakmakli, B; Hazer, B; Borcakli, M


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{
  "URL": "https://aperta.ulakbim.gov.tr/record/95481", 
  "abstract": "A new soluble terephthaloyl oligoperoxide (OTP) was synthesized by the reaction of terephthaloyl peroxide and 2.5-dimethyl 2,5-dihydroperoxy hexane. Thermal polymerization of vinyl monomers (styrene, methyl methacrylate) with OTP yielded poly(styrene peroxide) (PS-P) and poly(methyl methacrylate peroxide) (PMMA-P) which are used in the grafting reactions onto medium chain length unsaturated bacterial polyester obtained from soybean oily acids with Pseudomonas oleovorans poly(3-hydroxy alkanoate), (PHA). PS-g-PHA and PMMA-g-PHA graft copolymers isolated from related homopolymers were characterizated by H-1 NMR spectrometry, FT-IR spectroscopy, thermal analysis and gel permeation chromatographic (GPC) techniques. Swelling measurement of the crosslink-ed graft copolymers were also measured to calculate q(v) values.", 
  "author": [
    {
      "family": "Cakmakli", 
      "given": " B"
    }, 
    {
      "family": "Hazer", 
      "given": " B"
    }, 
    {
      "family": "Borcakli", 
      "given": " M"
    }
  ], 
  "container_title": "MACROMOLECULAR BIOSCIENCE", 
  "id": "95481", 
  "issue": "8", 
  "issued": {
    "date-parts": [
      [
        2001, 
        1, 
        1
      ]
    ]
  }, 
  "page": "348-354", 
  "title": "Poly(styrene peroxide) and poly(methyl methacrylate peroxide) for grafting on unsaturated bacterial polyesters", 
  "type": "article-journal", 
  "volume": "1"
}
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