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Isci, Uemit; Afanasiev, Pavel; Millet, Jean-Marc M.; Kudrik, Evgeny V.; Ahsen, Vefa; Sorokin, Alexander B.
{ "@context": "https://schema.org/", "@id": 93697, "@type": "ScholarlyArticle", "creator": [ { "@type": "Person", "name": "Isci, Uemit" }, { "@type": "Person", "affiliation": "Univ Lyon 1, IRCELYON, CNRS, UMR 5256, F-69626 Villeurbanne, France", "name": "Afanasiev, Pavel" }, { "@type": "Person", "affiliation": "Univ Lyon 1, IRCELYON, CNRS, UMR 5256, F-69626 Villeurbanne, France", "name": "Millet, Jean-Marc M." }, { "@type": "Person", "affiliation": "Univ Lyon 1, IRCELYON, CNRS, UMR 5256, F-69626 Villeurbanne, France", "name": "Kudrik, Evgeny V." }, { "@type": "Person", "name": "Ahsen, Vefa" }, { "@type": "Person", "affiliation": "Univ Lyon 1, IRCELYON, CNRS, UMR 5256, F-69626 Villeurbanne, France", "name": "Sorokin, Alexander B." } ], "datePublished": "2009-01-01", "description": "mu-Nitrido-bis [tetra-(hexyl-sulfonyl)phthalocyaninatoiron] (3a) and mu-nitrido-bis [tetra-(tert-butylsulfonyl)phthalocyaninatoiron] (3b) complexes have been prepared and fully characterized by electrospray ionization mass spectrometry, UV-Vis, FTIR, EPR, Mossbauer techniques as well as by X-ray photoelectron and Fe K-edge X-ray absorption spectroscopies. Small changes at the periphery of the phthalocyanine ligand introduce a difference in the iron oxidation state. While 3b with tert-butyl substituents is a neutral complex with a mixed-valence Fe-3.5-N-Fe-3.5 structural unit, 3a having n-hexyl substituents is an oxidized cationic Fe-IV-N-Fe-IV complex. The structural parameters of N-bridged diiron phthalocyanine with a Fe-3.5-N-Fe-3.5 unit were determined for the first time. Iron atoms in 3b are displaced out of plane by 0.24 angstrom and the Fe-N bond distance of the linear Fe-N-Fe fragment is equal to 1.67 angstrom. Both complexes selectively catalyze benzylic oxidation of alkyl aromatic compounds by (BuOOH)-Bu-t. Toluene was oxidized to benzoic acid with 80% selectivity, and the total turnover number was as high as 197. p-Toluic acid was the principal product of p-xylene oxidation. In this case the turnover number achieved 587 substrate molecules per molecule of catalyst. The described catalytic system is complementary to the recently reported system based on mu-nitrido diiron tetrabutylphthalocyanine-H2O2 which effectively oxidizes the benzene ring.", "headline": "Preparation and characterization of mu-nitrido diiron phthalocyanines with electron-withdrawing substituents: application for catalytic aromatic oxidation", "identifier": 93697, "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", "license": "http://www.opendefinition.org/licenses/cc-by", "name": "Preparation and characterization of mu-nitrido diiron phthalocyanines with electron-withdrawing substituents: application for catalytic aromatic oxidation", "url": "https://aperta.ulakbim.gov.tr/record/93697" }
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