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Functionalization of Polysulfones by Click Chemistry

Toiserkani, Hojjat; Yilmaz, Gorkem; Yagci, Yusuf; Torun, Lokman


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        "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Toiserkani, Hojjat"
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      {
        "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Yilmaz, Gorkem"
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      {
        "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
        "name": "Yagci, Yusuf"
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      {
        "affiliation": "TUBITAK Marmara Res Ctr, Inst Chem, TR-41470 Gebze, Kocaeli, Turkey", 
        "name": "Torun, Lokman"
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    "description": "Functionalization of polysulfones by using \"Click\" chemistry is described for the example of a small fluorescent analyte propargylpyrene. First, PSUs were converted to azido-functionalized polymers by successive chloromethylation and azidation. Propargylpyrene was prepared independently as a fluorescent click component. Finally, the azido-functionalized PSUs were coupled with propargylpyrene with high efficiency by copper-catalyzed azide/alkyne click reactions. The final polymers and intermediates at various stages were characterized by H-1 NMR, FT-IR, GPC, UV-Vis, and fluorescence spectroscopy techniques.", 
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      "issue": "22", 
      "pages": "2389-2395", 
      "title": "MACROMOLECULAR CHEMISTRY AND PHYSICS", 
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