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Functionalization of Polysulfones by Click Chemistry

Toiserkani, Hojjat; Yilmaz, Gorkem; Yagci, Yusuf; Torun, Lokman


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{
  "DOI": "10.1002/macp.201000245", 
  "abstract": "Functionalization of polysulfones by using \"Click\" chemistry is described for the example of a small fluorescent analyte propargylpyrene. First, PSUs were converted to azido-functionalized polymers by successive chloromethylation and azidation. Propargylpyrene was prepared independently as a fluorescent click component. Finally, the azido-functionalized PSUs were coupled with propargylpyrene with high efficiency by copper-catalyzed azide/alkyne click reactions. The final polymers and intermediates at various stages were characterized by H-1 NMR, FT-IR, GPC, UV-Vis, and fluorescence spectroscopy techniques.", 
  "author": [
    {
      "family": "Toiserkani", 
      "given": " Hojjat"
    }, 
    {
      "family": "Yilmaz", 
      "given": " Gorkem"
    }, 
    {
      "family": "Yagci", 
      "given": " Yusuf"
    }, 
    {
      "family": "Torun", 
      "given": " Lokman"
    }
  ], 
  "container_title": "MACROMOLECULAR CHEMISTRY AND PHYSICS", 
  "id": "92891", 
  "issue": "22", 
  "issued": {
    "date-parts": [
      [
        2010, 
        1, 
        1
      ]
    ]
  }, 
  "page": "2389-2395", 
  "title": "Functionalization of Polysulfones by Click Chemistry", 
  "type": "article-journal", 
  "volume": "211"
}
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