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Synthesis of Thienyl-Substituted Dihydrofuran Compounds Promoted by Manganese(III) Acetate

Bicer, Emre; Yilmaz, Mehmet; Burgaz, E. Vildan; Pekel, A. Tarik


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  <dc:creator>Bicer, Emre</dc:creator>
  <dc:creator>Yilmaz, Mehmet</dc:creator>
  <dc:creator>Burgaz, E. Vildan</dc:creator>
  <dc:creator>Pekel, A. Tarik</dc:creator>
  <dc:date>2013-01-01</dc:date>
  <dc:description>Radical cyclization reactions of both aliphatic 1,3-diones 1a and 1b and of cyclic 1,3-diones 1c1e with 2-thienyl- and 3-thienyl-substituted alkenes 2a2d in the presence of manganese(III) acetate were investigated. Thienyl-substituted dihydrofurans 3 were obtained with moderate to high yields (Table 13). Also, the favorable effect of the thienyl substituent on the intermediate carbocation stability was evaluated by comparison with a phenyl substituent.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/91809</dc:identifier>
  <dc:identifier>oai:zenodo.org:91809</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>HELVETICA CHIMICA ACTA 96(1) 135-141</dc:source>
  <dc:title>Synthesis of Thienyl-Substituted Dihydrofuran Compounds Promoted by Manganese(III) Acetate</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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