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Synthesis of Thienyl-Substituted Dihydrofuran Compounds Promoted by Manganese(III) Acetate

Bicer, Emre; Yilmaz, Mehmet; Burgaz, E. Vildan; Pekel, A. Tarik


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        "affiliation": "TUBITAK Marmara Res Ctr, Energy Inst, TR-41470 Gebze, Turkey", 
        "name": "Bicer, Emre"
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      {
        "affiliation": "Kocaeli Univ, Fac Arts & Sci, Dept Chem, TR-41380 Umuttepe Kocaeli, Turkey", 
        "name": "Yilmaz, Mehmet"
      }, 
      {
        "affiliation": "Ankara Univ, Fac Sci, Dept Chem, TR-06100 Tandogan, Turkey", 
        "name": "Burgaz, E. Vildan"
      }, 
      {
        "affiliation": "Ankara Univ, Fac Sci, Dept Chem, TR-06100 Tandogan, Turkey", 
        "name": "Pekel, A. Tarik"
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    "description": "Radical cyclization reactions of both aliphatic 1,3-diones 1a and 1b and of cyclic 1,3-diones 1c1e with 2-thienyl- and 3-thienyl-substituted alkenes 2a2d in the presence of manganese(III) acetate were investigated. Thienyl-substituted dihydrofurans 3 were obtained with moderate to high yields (Table 13). Also, the favorable effect of the thienyl substituent on the intermediate carbocation stability was evaluated by comparison with a phenyl substituent.", 
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    "title": "Synthesis of Thienyl-Substituted Dihydrofuran Compounds Promoted by Manganese(III) Acetate"
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