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Synthesis of Thienyl-Substituted Dihydrofuran Compounds Promoted by Manganese(III) Acetate

Bicer, Emre; Yilmaz, Mehmet; Burgaz, E. Vildan; Pekel, A. Tarik


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/91809</identifier>
  <creators>
    <creator>
      <creatorName>Bicer, Emre</creatorName>
      <givenName>Emre</givenName>
      <familyName>Bicer</familyName>
      <affiliation>TUBITAK Marmara Res Ctr, Energy Inst, TR-41470 Gebze, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yilmaz, Mehmet</creatorName>
      <givenName>Mehmet</givenName>
      <familyName>Yilmaz</familyName>
      <affiliation>Kocaeli Univ, Fac Arts &amp; Sci, Dept Chem, TR-41380 Umuttepe Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Burgaz, E. Vildan</creatorName>
      <givenName>E. Vildan</givenName>
      <familyName>Burgaz</familyName>
      <affiliation>Ankara Univ, Fac Sci, Dept Chem, TR-06100 Tandogan, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Pekel, A. Tarik</creatorName>
      <givenName>A. Tarik</givenName>
      <familyName>Pekel</familyName>
      <affiliation>Ankara Univ, Fac Sci, Dept Chem, TR-06100 Tandogan, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis Of Thienyl-Substituted Dihydrofuran Compounds Promoted By Manganese(Iii) Acetate</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/91809</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1002/hlca.201200098</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Radical cyclization reactions of both aliphatic 1,3-diones 1a and 1b and of cyclic 1,3-diones 1c1e with 2-thienyl- and 3-thienyl-substituted alkenes 2a2d in the presence of manganese(III) acetate were investigated. Thienyl-substituted dihydrofurans 3 were obtained with moderate to high yields (Table 13). Also, the favorable effect of the thienyl substituent on the intermediate carbocation stability was evaluated by comparison with a phenyl substituent.</description>
  </descriptions>
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