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The Fast-Track Water Oxidation Channel on BiVO4 Opened by Nitrogen Treatment

Kahraman, Abdullah; Vishlaghi, Mahsa Barzgar; Baylam, Isinsu; Ogasawara, Hirohito; Sennaroglu, Alphan; Kaya, Sarp


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  <dc:creator>Kahraman, Abdullah</dc:creator>
  <dc:creator>Vishlaghi, Mahsa Barzgar</dc:creator>
  <dc:creator>Baylam, Isinsu</dc:creator>
  <dc:creator>Ogasawara, Hirohito</dc:creator>
  <dc:creator>Sennaroglu, Alphan</dc:creator>
  <dc:creator>Kaya, Sarp</dc:creator>
  <dc:date>2020-01-01</dc:date>
  <dc:description>BiVO4 is one of the most promising photoanode materials for water-splitting systems. Nitrogen incorporation into a BiVO4 surface overcomes the known bottleneck in its charge-transfer kinetics into the electrolyte. We explored the role of nitrogen in the surface charge recombination and charge-transfer kinetics by employing transient photocurrent spectroscopy at the time scale of surface recombination and water oxidation kinetics, transient absorption spectroscopy, and X-ray photoelectron spectroscopy. We attributed the activity enhancement mechanism to the accelerated V5+/V4+ redox process, in which incorporated nitrogen suppresses a limiting surface recombination channel by increasing the oxygen vacancies.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/8809</dc:identifier>
  <dc:identifier>oai:zenodo.org:8809</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF PHYSICAL CHEMISTRY LETTERS 11(20) 8758-8764</dc:source>
  <dc:title>The Fast-Track Water Oxidation Channel on BiVO4 Opened by Nitrogen Treatment</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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