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The Fast-Track Water Oxidation Channel on BiVO4 Opened by Nitrogen Treatment

Kahraman, Abdullah; Vishlaghi, Mahsa Barzgar; Baylam, Isinsu; Ogasawara, Hirohito; Sennaroglu, Alphan; Kaya, Sarp


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/8809</identifier>
  <creators>
    <creator>
      <creatorName>Kahraman, Abdullah</creatorName>
      <givenName>Abdullah</givenName>
      <familyName>Kahraman</familyName>
    </creator>
    <creator>
      <creatorName>Vishlaghi, Mahsa Barzgar</creatorName>
      <givenName>Mahsa Barzgar</givenName>
      <familyName>Vishlaghi</familyName>
    </creator>
    <creator>
      <creatorName>Baylam, Isinsu</creatorName>
      <givenName>Isinsu</givenName>
      <familyName>Baylam</familyName>
      <affiliation>Koc Univ Surface Sci &amp; Technol Ctr KUYTAM, TR-34450 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ogasawara, Hirohito</creatorName>
      <givenName>Hirohito</givenName>
      <familyName>Ogasawara</familyName>
      <affiliation>SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA</affiliation>
    </creator>
    <creator>
      <creatorName>Sennaroglu, Alphan</creatorName>
      <givenName>Alphan</givenName>
      <familyName>Sennaroglu</familyName>
    </creator>
    <creator>
      <creatorName>Kaya, Sarp</creatorName>
      <givenName>Sarp</givenName>
      <familyName>Kaya</familyName>
    </creator>
  </creators>
  <titles>
    <title>The Fast-Track Water Oxidation Channel On Bivo4 Opened By Nitrogen Treatment</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2020</publicationYear>
  <dates>
    <date dateType="Issued">2020-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/8809</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1021/acs.jpclett.0c02190</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">BiVO4 is one of the most promising photoanode materials for water-splitting systems. Nitrogen incorporation into a BiVO4 surface overcomes the known bottleneck in its charge-transfer kinetics into the electrolyte. We explored the role of nitrogen in the surface charge recombination and charge-transfer kinetics by employing transient photocurrent spectroscopy at the time scale of surface recombination and water oxidation kinetics, transient absorption spectroscopy, and X-ray photoelectron spectroscopy. We attributed the activity enhancement mechanism to the accelerated V5+/V4+ redox process, in which incorporated nitrogen suppresses a limiting surface recombination channel by increasing the oxygen vacancies.</description>
  </descriptions>
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