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The Fast-Track Water Oxidation Channel on BiVO4 Opened by Nitrogen Treatment

Kahraman, Abdullah; Vishlaghi, Mahsa Barzgar; Baylam, Isinsu; Ogasawara, Hirohito; Sennaroglu, Alphan; Kaya, Sarp


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        "name": "Vishlaghi, Mahsa Barzgar"
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        "affiliation": "Koc Univ Surface Sci & Technol Ctr KUYTAM, TR-34450 Istanbul, Turkey", 
        "name": "Baylam, Isinsu"
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      {
        "affiliation": "SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA", 
        "name": "Ogasawara, Hirohito"
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      {
        "name": "Sennaroglu, Alphan"
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      {
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    "description": "BiVO4 is one of the most promising photoanode materials for water-splitting systems. Nitrogen incorporation into a BiVO4 surface overcomes the known bottleneck in its charge-transfer kinetics into the electrolyte. We explored the role of nitrogen in the surface charge recombination and charge-transfer kinetics by employing transient photocurrent spectroscopy at the time scale of surface recombination and water oxidation kinetics, transient absorption spectroscopy, and X-ray photoelectron spectroscopy. We attributed the activity enhancement mechanism to the accelerated V5+/V4+ redox process, in which incorporated nitrogen suppresses a limiting surface recombination channel by increasing the oxygen vacancies.", 
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