1 Ocak 2012 Dergi makalesi Açık Erişim

Solpan, Dilek; Torun, Murat

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        "affiliation": "Hacettepe Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Solpan, Dilek"
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        "affiliation": "Hacettepe Univ, Dept Chem, TR-06800 Ankara, Turkey", 
        "name": "Torun, Murat"
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    "description": "In this study, the radiation-induced degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) herbicide in aqueous solution was studied under various conditions as a function of irradiation dose in the absence and presence of hydrogen peroxide. The obtained data confirmed that largest yield of radiolytic degradation is obtained in oxidation processes/ionizing radiation, where oxidation is carried out with hydroxyl radicals. For complete degradation of 50 ppm 2,4-D, a required dose was lower in the presence of hydrogen peroxide. The formed major toxic phenolic intermediates were 2,4-dichlorophenol (2,4-DCP) and 4-chlorophenol (4-CP). The chemical analysis of the 2,4-D and the intermediates resulted from the radiolytic degradation were performed using a gas chromatography associated to mass spectrometry (GC-MS) with ion trap dedector (ITD) and ion chromatography (IC). The formation of chlorophenols in addition to chloride, formaldehyde and carboxylic acids was studied as a function of absorbed dose.", 
    "doi": "10.1007/s10967-012-1771-5", 
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    "journal": {
      "issue": "1", 
      "pages": "21-38", 
      "title": "JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY", 
      "volume": "293"
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    "publication_date": "2012-01-01", 
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    "title": "The removal of chlorinated organic herbicide in water by gamma-irradiation"
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