1 Ocak 2012 Dergi makalesi Açık Erişim

Solpan, Dilek; Torun, Murat

Citation Style Language JSON

{
  "DOI": "10.1007/s10967-012-1771-5", 
  "abstract": "In this study, the radiation-induced degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) herbicide in aqueous solution was studied under various conditions as a function of irradiation dose in the absence and presence of hydrogen peroxide. The obtained data confirmed that largest yield of radiolytic degradation is obtained in oxidation processes/ionizing radiation, where oxidation is carried out with hydroxyl radicals. For complete degradation of 50 ppm 2,4-D, a required dose was lower in the presence of hydrogen peroxide. The formed major toxic phenolic intermediates were 2,4-dichlorophenol (2,4-DCP) and 4-chlorophenol (4-CP). The chemical analysis of the 2,4-D and the intermediates resulted from the radiolytic degradation were performed using a gas chromatography associated to mass spectrometry (GC-MS) with ion trap dedector (ITD) and ion chromatography (IC). The formation of chlorophenols in addition to chloride, formaldehyde and carboxylic acids was studied as a function of absorbed dose.", 
  "author": [
    {
      "family": "Solpan", 
      "given": " Dilek"
    }, 
    {
      "family": "Torun", 
      "given": " Murat"
    }
  ], 
  "container_title": "JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY", 
  "id": "86025", 
  "issue": "1", 
  "issued": {
    "date-parts": [
      [
        2012, 
        1, 
        1
      ]
    ]
  }, 
  "page": "21-38", 
  "title": "The removal of chlorinated organic herbicide in water by gamma-irradiation", 
  "type": "article-journal", 
  "volume": "293"
}