1 Ocak 2019 Dergi makalesi Açık Erişim

Gok, Halil Zeki; Gok, Yasar

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  <dc:creator>Gok, Halil Zeki</dc:creator>
  <dc:creator>Gok, Yasar</dc:creator>
  <dc:date>2019-01-01</dc:date>
  <dc:description>A novel bisphthalonitrile 5,5-(pentane-1,5-diylbis(sulfanediyl))bis(4-((2-aminophenyl)thio)phthalonitrile) 2 was synthesized by a nucleophilic aromatic substitution of chloro atom of 4-(2-aminophenyl sulfanyl)-5-chloro-benzene-1,2-dicarbonitrile 1 with dithiol functions of pentane-1,5-dithiole. The synthesis of polymeric phthalocyanine complexes 3 and 4 by cyclotetramerization of bisphthalonitrile derivative 2 were accomplished in the presence of appropriate metal salt in a Schlenk tube containing quinoline under nitrogen atmosphere. The investigation of metal-ion binding properties of bisphthalonitrile 2 and polymeric zinc(II) phthalocyanine 4 was performed by using liquid-liquid extraction procedure for 2 and solid-liquid extraction procedure for 4. Polymeric zinc(II) phthalocyanine 4 was found to extract Ag(II) and Hg(II) with high efficiency. The novel compounds were characterized by a combination of elemental analysis and H-1 NMR, C-13 NMR, IR, and MS spectral data.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/74269</dc:identifier>
  <dc:identifier>oai:zenodo.org:74269</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY 94(1-2) 55-63</dc:source>
  <dc:title>Novel polymeric phthalocyanines bridged flexible 1,5-pentanedithiol unit for metal ions extraction: synthesis, characterization and evaluation</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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