1 Ocak 2019 Dergi makalesi Açık Erişim

Gok, Halil Zeki; Gok, Yasar

Citation Style Language JSON

{
  "DOI": "10.1007/s10847-019-00901-1", 
  "abstract": "A novel bisphthalonitrile 5,5-(pentane-1,5-diylbis(sulfanediyl))bis(4-((2-aminophenyl)thio)phthalonitrile) 2 was synthesized by a nucleophilic aromatic substitution of chloro atom of 4-(2-aminophenyl sulfanyl)-5-chloro-benzene-1,2-dicarbonitrile 1 with dithiol functions of pentane-1,5-dithiole. The synthesis of polymeric phthalocyanine complexes 3 and 4 by cyclotetramerization of bisphthalonitrile derivative 2 were accomplished in the presence of appropriate metal salt in a Schlenk tube containing quinoline under nitrogen atmosphere. The investigation of metal-ion binding properties of bisphthalonitrile 2 and polymeric zinc(II) phthalocyanine 4 was performed by using liquid-liquid extraction procedure for 2 and solid-liquid extraction procedure for 4. Polymeric zinc(II) phthalocyanine 4 was found to extract Ag(II) and Hg(II) with high efficiency. The novel compounds were characterized by a combination of elemental analysis and H-1 NMR, C-13 NMR, IR, and MS spectral data.", 
  "author": [
    {
      "family": "Gok", 
      "given": " Halil Zeki"
    }, 
    {
      "family": "Gok", 
      "given": " Yasar"
    }
  ], 
  "container_title": "JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY", 
  "id": "74269", 
  "issue": "1-2", 
  "issued": {
    "date-parts": [
      [
        2019, 
        1, 
        1
      ]
    ]
  }, 
  "page": "55-63", 
  "title": "Novel polymeric phthalocyanines bridged flexible 1,5-pentanedithiol unit for metal ions extraction: synthesis, characterization and evaluation", 
  "type": "article-journal", 
  "volume": "94"
}