1 Ocak 2019 Dergi makalesi Açık Erişim

Gok, Halil Zeki; Gok, Yasar

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/74269</identifier>
  <creators>
    <creator>
      <creatorName>Gok, Halil Zeki</creatorName>
      <givenName>Halil Zeki</givenName>
      <familyName>Gok</familyName>
      <affiliation>Burdur Mehmet Akif Ersoy Univ, Bucak Technol Fac, Dept Biomed Engn, TR-15300 Bucak, Burdur, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gok, Yasar</creatorName>
      <givenName>Yasar</givenName>
      <familyName>Gok</familyName>
      <affiliation>Burdur Mehmet Akif Ersoy Univ, Bucak Technol Fac, Dept Biomed Engn, TR-15300 Bucak, Burdur, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Novel Polymeric Phthalocyanines Bridged Flexible 1,5-Pentanedithiol Unit For Metal Ions Extraction: Synthesis, Characterization And Evaluation</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2019</publicationYear>
  <dates>
    <date dateType="Issued">2019-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/74269</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1007/s10847-019-00901-1</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A novel bisphthalonitrile 5,5-(pentane-1,5-diylbis(sulfanediyl))bis(4-((2-aminophenyl)thio)phthalonitrile) 2 was synthesized by a nucleophilic aromatic substitution of chloro atom of 4-(2-aminophenyl sulfanyl)-5-chloro-benzene-1,2-dicarbonitrile 1 with dithiol functions of pentane-1,5-dithiole. The synthesis of polymeric phthalocyanine complexes 3 and 4 by cyclotetramerization of bisphthalonitrile derivative 2 were accomplished in the presence of appropriate metal salt in a Schlenk tube containing quinoline under nitrogen atmosphere. The investigation of metal-ion binding properties of bisphthalonitrile 2 and polymeric zinc(II) phthalocyanine 4 was performed by using liquid-liquid extraction procedure for 2 and solid-liquid extraction procedure for 4. Polymeric zinc(II) phthalocyanine 4 was found to extract Ag(II) and Hg(II) with high efficiency. The novel compounds were characterized by a combination of elemental analysis and H-1 NMR, C-13 NMR, IR, and MS spectral data.</description>
  </descriptions>
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