1 Ocak 2019 Dergi makalesi Açık Erişim

Yildiz, Burak; Guzel, Emre; Akyuz, Duygu; Arslan, Baris Seckin; Koca, Atif; Sener, M. Kasim

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    <subfield code="a">A new photosensitizer, PCA-ZnPc-2, was synthesized through the asymmetric functionalization of phthalocyanine ring with a pyrazole-3-carboxylic acid as the electron-withdrawing and anchoring group and six hexylsulfanyl as the bulky electron-donating groups. PCA-ZnPc-2 was tested in dye-sensitized solar cells (DSSCs) and its performance was compared with PCA-ZnPc-1. It was found that PCA-ZnPc-2 has higher electron-donating ability which is favorable for light harvesting and suppress the dye aggregation on TiO2 when compared to PCA-ZnPc-1. Also, the new photosensitizer was used in dye-sensitized photoelectrochemical cells for hydrogen production under visible irradiation. The results show that PCA-ZnPc-2 is a promising photosensitizer to harvest the red/near-IR regions.</subfield>
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