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Unsymmetrically pyrazole-3-carboxylic acid substituted phthalocyanine-based photoanodes for use in water splitting photoelectrochemical and dye-sensitized solar cells

Yildiz, Burak; Guzel, Emre; Akyuz, Duygu; Arslan, Baris Seckin; Koca, Atif; Sener, M. Kasim


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        "affiliation": "Yildiz Tech Univ, Dept Chem, TR-34210 Istanbul, Turkey", 
        "name": "Yildiz, Burak"
      }, 
      {
        "affiliation": "Sakarya Univ, Dept Chem, TR-54050 Sakarya, Turkey", 
        "name": "Guzel, Emre"
      }, 
      {
        "affiliation": "Marmara Univ, Dept Chem Engn, TR-34722 Istanbul, Turkey", 
        "name": "Akyuz, Duygu"
      }, 
      {
        "affiliation": "Sakarya Univ, Dept Chem, TR-54050 Sakarya, Turkey", 
        "name": "Arslan, Baris Seckin"
      }, 
      {
        "affiliation": "Marmara Univ, Dept Chem Engn, TR-34722 Istanbul, Turkey", 
        "name": "Koca, Atif"
      }, 
      {
        "affiliation": "Yildiz Tech Univ, Dept Chem, TR-34210 Istanbul, Turkey", 
        "name": "Sener, M. Kasim"
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    "description": "A new photosensitizer, PCA-ZnPc-2, was synthesized through the asymmetric functionalization of phthalocyanine ring with a pyrazole-3-carboxylic acid as the electron-withdrawing and anchoring group and six hexylsulfanyl as the bulky electron-donating groups. PCA-ZnPc-2 was tested in dye-sensitized solar cells (DSSCs) and its performance was compared with PCA-ZnPc-1. It was found that PCA-ZnPc-2 has higher electron-donating ability which is favorable for light harvesting and suppress the dye aggregation on TiO2 when compared to PCA-ZnPc-1. Also, the new photosensitizer was used in dye-sensitized photoelectrochemical cells for hydrogen production under visible irradiation. The results show that PCA-ZnPc-2 is a promising photosensitizer to harvest the red/near-IR regions.", 
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      "pages": "654-662", 
      "title": "SOLAR ENERGY", 
      "volume": "191"
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