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Unsymmetrically pyrazole-3-carboxylic acid substituted phthalocyanine-based photoanodes for use in water splitting photoelectrochemical and dye-sensitized solar cells

Yildiz, Burak; Guzel, Emre; Akyuz, Duygu; Arslan, Baris Seckin; Koca, Atif; Sener, M. Kasim


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{
  "DOI": "10.1016/j.solener.2019.09.043", 
  "abstract": "A new photosensitizer, PCA-ZnPc-2, was synthesized through the asymmetric functionalization of phthalocyanine ring with a pyrazole-3-carboxylic acid as the electron-withdrawing and anchoring group and six hexylsulfanyl as the bulky electron-donating groups. PCA-ZnPc-2 was tested in dye-sensitized solar cells (DSSCs) and its performance was compared with PCA-ZnPc-1. It was found that PCA-ZnPc-2 has higher electron-donating ability which is favorable for light harvesting and suppress the dye aggregation on TiO2 when compared to PCA-ZnPc-1. Also, the new photosensitizer was used in dye-sensitized photoelectrochemical cells for hydrogen production under visible irradiation. The results show that PCA-ZnPc-2 is a promising photosensitizer to harvest the red/near-IR regions.", 
  "author": [
    {
      "family": "Yildiz", 
      "given": " Burak"
    }, 
    {
      "family": "Guzel", 
      "given": " Emre"
    }, 
    {
      "family": "Akyuz", 
      "given": " Duygu"
    }, 
    {
      "family": "Arslan", 
      "given": " Baris Seckin"
    }, 
    {
      "family": "Koca", 
      "given": " Atif"
    }, 
    {
      "family": "Sener", 
      "given": " M. Kasim"
    }
  ], 
  "container_title": "SOLAR ENERGY", 
  "id": "68869", 
  "issued": {
    "date-parts": [
      [
        2019, 
        1, 
        1
      ]
    ]
  }, 
  "page": "654-662", 
  "title": "Unsymmetrically pyrazole-3-carboxylic acid substituted phthalocyanine-based photoanodes for use in water splitting photoelectrochemical and dye-sensitized solar cells", 
  "type": "article-journal", 
  "volume": "191"
}
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