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Structural and magnetic studies of TiO2 rutile implanted with vanadium ions

Vakhitov, I. R.; Shemukhin, A. A.; Gumarov, A., I; Lyadov, N. M.; Nuzhdin, V., I; Faizrakhmanov, I. A.; Okay, C.; Rameev, B. Z.; Tagirov, L. R.; Khaibullin, R., I


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    "creators": [
      {
        "affiliation": "Kazan Fed Univ, Inst Phys, Kazan, Russia", 
        "name": "Vakhitov, I. R."
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      {
        "affiliation": "Lomonosov Moscow State Univ, Skobeltsyn Inst Nucl Phys, Moscow, Russia", 
        "name": "Shemukhin, A. A."
      }, 
      {
        "affiliation": "Kazan Fed Univ, Inst Phys, Kazan, Russia", 
        "name": "Gumarov, A., I"
      }, 
      {
        "affiliation": "RAS, Zavoisky Phys Tech Inst, FRC Kazan Sci Ctr, Kazan, Russia", 
        "name": "Lyadov, N. M."
      }, 
      {
        "affiliation": "RAS, Zavoisky Phys Tech Inst, FRC Kazan Sci Ctr, Kazan, Russia", 
        "name": "Nuzhdin, V., I"
      }, 
      {
        "affiliation": "RAS, Zavoisky Phys Tech Inst, FRC Kazan Sci Ctr, Kazan, Russia", 
        "name": "Faizrakhmanov, I. A."
      }, 
      {
        "affiliation": "Marmara Univ, Istanbul, Turkey", 
        "name": "Okay, C."
      }, 
      {
        "name": "Rameev, B. Z."
      }, 
      {
        "name": "Tagirov, L. R."
      }, 
      {
        "affiliation": "RAS, Zavoisky Phys Tech Inst, FRC Kazan Sci Ctr, Kazan, Russia", 
        "name": "Khaibullin, R., I"
      }
    ], 
    "description": "Single crystal (100) and (001) TiO2 rutile plates were implanted with vanadium 40 keV ions to the fluence of 1.5 x 10(17) ion cm(-2). A set of samples was also annealed at high-temperature in air to restore oxygen stoichiometric content and recover the TiO2 lattice structure after the high-dose ion implantation. In addition, a control set of TiO2 rutile plates was implanted with 40 keV argon ions to the same fluence to explore the effect of radiation-induced defects on magnetic properties. Rutherford backscattering spectroscopy (RBS), x-ray photoelectron spectroscopy (XPS) and vibrating sample magnetometry (VSM) measurements were carried out to characterize the structural and magnetic properties of the vanadium-implanted TiO2. Both as-implanted and subsequently annealed V-TiO2 samples reveal ferromagnetic response at room temperature. Strong ferromagnetism observed in the vanadium-implanted (001) TiO2 plates is related to the \\substitutional V4+ ions coupled by the indirect exchange via electrons trapped at oxygen vacancies, while much weaker ferromagnetism in the (100)oriented plates and the Ar-implanted samples is attributed to lattice defects induced by the high-dose ion irradiation. Suppression of the ferromagnetic response in the vanadium-implanted (001) TiO2 after the thermal treatment is explained by filling in the oxygen vacancies due to oxygen diffusion during annealing in air atmosphere.", 
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      "issue": "11", 
      "title": "MATERIALS RESEARCH EXPRESS", 
      "volume": "6"
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    "publication_date": "2019-01-01", 
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    "title": "Structural and magnetic studies of TiO2 rutile implanted with vanadium ions"
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