1 Ocak 2019 Dergi makalesi Açık Erişim

Vakhitov, I. R.; Shemukhin, A. A.; Gumarov, A., I; Lyadov, N. M.; Nuzhdin, V., I; Faizrakhmanov, I. A.; Okay, C.; Rameev, B. Z.; Tagirov, L. R.; Khaibullin, R., I

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{
  "DOI": "10.1088/2053-1591/ab447e", 
  "abstract": "Single crystal (100) and (001) TiO2 rutile plates were implanted with vanadium 40 keV ions to the fluence of 1.5 x 10(17) ion cm(-2). A set of samples was also annealed at high-temperature in air to restore oxygen stoichiometric content and recover the TiO2 lattice structure after the high-dose ion implantation. In addition, a control set of TiO2 rutile plates was implanted with 40 keV argon ions to the same fluence to explore the effect of radiation-induced defects on magnetic properties. Rutherford backscattering spectroscopy (RBS), x-ray photoelectron spectroscopy (XPS) and vibrating sample magnetometry (VSM) measurements were carried out to characterize the structural and magnetic properties of the vanadium-implanted TiO2. Both as-implanted and subsequently annealed V-TiO2 samples reveal ferromagnetic response at room temperature. Strong ferromagnetism observed in the vanadium-implanted (001) TiO2 plates is related to the \\substitutional V4+ ions coupled by the indirect exchange via electrons trapped at oxygen vacancies, while much weaker ferromagnetism in the (100)oriented plates and the Ar-implanted samples is attributed to lattice defects induced by the high-dose ion irradiation. Suppression of the ferromagnetic response in the vanadium-implanted (001) TiO2 after the thermal treatment is explained by filling in the oxygen vacancies due to oxygen diffusion during annealing in air atmosphere.", 
  "author": [
    {
      "family": "Vakhitov", 
      "given": " I. R."
    }, 
    {
      "family": "Shemukhin", 
      "given": " A. A."
    }, 
    {
      "family": "Gumarov", 
      "given": " A."
    }, 
    {
      "family": "Lyadov", 
      "given": " N. M."
    }, 
    {
      "family": "Nuzhdin", 
      "given": " V."
    }, 
    {
      "family": "Faizrakhmanov", 
      "given": " I. A."
    }, 
    {
      "family": "Okay", 
      "given": " C."
    }, 
    {
      "family": "Rameev", 
      "given": " B. Z."
    }, 
    {
      "family": "Tagirov", 
      "given": " L. R."
    }, 
    {
      "family": "Khaibullin", 
      "given": " R."
    }
  ], 
  "container_title": "MATERIALS RESEARCH EXPRESS", 
  "id": "67983", 
  "issue": "11", 
  "issued": {
    "date-parts": [
      [
        2019, 
        1, 
        1
      ]
    ]
  }, 
  "title": "Structural and magnetic studies of TiO2 rutile implanted with vanadium ions", 
  "type": "article-journal", 
  "volume": "6"
}