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Thiol-ene-clickable and emissive carbazole-based polymer networks with tunable colors

Doyranli, Ceylan; Buyukcelebi, Sumeyra; Koyuncu, Sermet; Usluer, Ozlem; Kus, Mahmut; Koyuncu, Fatma Baycan


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  <dc:creator>Doyranli, Ceylan</dc:creator>
  <dc:creator>Buyukcelebi, Sumeyra</dc:creator>
  <dc:creator>Koyuncu, Sermet</dc:creator>
  <dc:creator>Usluer, Ozlem</dc:creator>
  <dc:creator>Kus, Mahmut</dc:creator>
  <dc:creator>Koyuncu, Fatma Baycan</dc:creator>
  <dc:date>2016-01-01</dc:date>
  <dc:description>Band gap tuning and processability of organic materials are significant topics for both scientific research and commercial applications. In this study, we synthesized a series of main chain cross-linkable polymers by thiol-ene click chemistry from N-allyl carbazole and different heterocycles via conventional Suzuki coupling polymerization reaction. The emission color of polymers could be successfully tuned from blue to red by attaching different benzazole-acceptor moieties to the carbazole donor unit. We also investigated the effects of cross-linking with respect to the amount of pentaerythritol tetrakis(3-mercaptopropionate) cross-linker on the optical, electrochemical, and surface morphological properties of the polymer films. The results showed that these polymers can be used as emissive active layers in solution-processable multilayer organic light-emitting diodes. (C) 2016 Published by Elsevier B.V.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/60383</dc:identifier>
  <dc:identifier>oai:zenodo.org:60383</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>REACTIVE &amp; FUNCTIONAL POLYMERS 106 17-23</dc:source>
  <dc:title>Thiol-ene-clickable and emissive carbazole-based polymer networks with tunable colors</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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