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Thiol-ene-clickable and emissive carbazole-based polymer networks with tunable colors

Doyranli, Ceylan; Buyukcelebi, Sumeyra; Koyuncu, Sermet; Usluer, Ozlem; Kus, Mahmut; Koyuncu, Fatma Baycan


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{
  "DOI": "10.1016/j.reactfunctpolym.2016.07.003", 
  "abstract": "Band gap tuning and processability of organic materials are significant topics for both scientific research and commercial applications. In this study, we synthesized a series of main chain cross-linkable polymers by thiol-ene click chemistry from N-allyl carbazole and different heterocycles via conventional Suzuki coupling polymerization reaction. The emission color of polymers could be successfully tuned from blue to red by attaching different benzazole-acceptor moieties to the carbazole donor unit. We also investigated the effects of cross-linking with respect to the amount of pentaerythritol tetrakis(3-mercaptopropionate) cross-linker on the optical, electrochemical, and surface morphological properties of the polymer films. The results showed that these polymers can be used as emissive active layers in solution-processable multilayer organic light-emitting diodes. (C) 2016 Published by Elsevier B.V.", 
  "author": [
    {
      "family": "Doyranli", 
      "given": " Ceylan"
    }, 
    {
      "family": "Buyukcelebi", 
      "given": " Sumeyra"
    }, 
    {
      "family": "Koyuncu", 
      "given": " Sermet"
    }, 
    {
      "family": "Usluer", 
      "given": " Ozlem"
    }, 
    {
      "family": "Kus", 
      "given": " Mahmut"
    }, 
    {
      "family": "Koyuncu", 
      "given": " Fatma Baycan"
    }
  ], 
  "container_title": "REACTIVE & FUNCTIONAL POLYMERS", 
  "id": "60383", 
  "issued": {
    "date-parts": [
      [
        2016, 
        1, 
        1
      ]
    ]
  }, 
  "page": "17-23", 
  "title": "Thiol-ene-clickable and emissive carbazole-based polymer networks with tunable colors", 
  "type": "article-journal", 
  "volume": "106"
}
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