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Thiol-ene-clickable and emissive carbazole-based polymer networks with tunable colors

Doyranli, Ceylan; Buyukcelebi, Sumeyra; Koyuncu, Sermet; Usluer, Ozlem; Kus, Mahmut; Koyuncu, Fatma Baycan


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/60383</identifier>
  <creators>
    <creator>
      <creatorName>Doyranli, Ceylan</creatorName>
      <givenName>Ceylan</givenName>
      <familyName>Doyranli</familyName>
    </creator>
    <creator>
      <creatorName>Buyukcelebi, Sumeyra</creatorName>
      <givenName>Sumeyra</givenName>
      <familyName>Buyukcelebi</familyName>
      <affiliation>Selcuk Univ, Adv Technol Res &amp; Applicat Ctr, TR-42075 Konya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Koyuncu, Sermet</creatorName>
      <givenName>Sermet</givenName>
      <familyName>Koyuncu</familyName>
      <affiliation>Canakkale Onsekiz Mart Univ, Dept Chem Engn, Fac Engn, TR-17020 Canakkale, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Usluer, Ozlem</creatorName>
      <givenName>Ozlem</givenName>
      <familyName>Usluer</familyName>
    </creator>
    <creator>
      <creatorName>Kus, Mahmut</creatorName>
      <givenName>Mahmut</givenName>
      <familyName>Kus</familyName>
    </creator>
    <creator>
      <creatorName>Koyuncu, Fatma Baycan</creatorName>
      <givenName>Fatma Baycan</givenName>
      <familyName>Koyuncu</familyName>
    </creator>
  </creators>
  <titles>
    <title>Thiol-Ene-Clickable And Emissive Carbazole-Based Polymer Networks With Tunable Colors</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2016</publicationYear>
  <dates>
    <date dateType="Issued">2016-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/60383</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.reactfunctpolym.2016.07.003</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Band gap tuning and processability of organic materials are significant topics for both scientific research and commercial applications. In this study, we synthesized a series of main chain cross-linkable polymers by thiol-ene click chemistry from N-allyl carbazole and different heterocycles via conventional Suzuki coupling polymerization reaction. The emission color of polymers could be successfully tuned from blue to red by attaching different benzazole-acceptor moieties to the carbazole donor unit. We also investigated the effects of cross-linking with respect to the amount of pentaerythritol tetrakis(3-mercaptopropionate) cross-linker on the optical, electrochemical, and surface morphological properties of the polymer films. The results showed that these polymers can be used as emissive active layers in solution-processable multilayer organic light-emitting diodes. (C) 2016 Published by Elsevier B.V.</description>
  </descriptions>
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