1 Ocak 2016 Dergi makalesi Açık Erişim

Kucukturkmen, Cigdem; Agac, Ahmet; Eren, Aysel; Karakaya, Idris; Aslantas, Mehmet; Celik, Omer; Ulukanli, Sabri; Karabuga, Semistan

Dublin Core

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  <dc:creator>Kucukturkmen, Cigdem</dc:creator>
  <dc:creator>Agac, Ahmet</dc:creator>
  <dc:creator>Eren, Aysel</dc:creator>
  <dc:creator>Karakaya, Idris</dc:creator>
  <dc:creator>Aslantas, Mehmet</dc:creator>
  <dc:creator>Celik, Omer</dc:creator>
  <dc:creator>Ulukanli, Sabri</dc:creator>
  <dc:creator>Karabuga, Semistan</dc:creator>
  <dc:date>2016-01-01</dc:date>
  <dc:description>The novel set of quinazoline-based chiral ligands was synthesized starting from optically pure amino acids. Coordination with RuCl2(PPh3)dppb gave ruthenium(II) N-heterocyclic complexes 4b-d. The structure of complex 4b was fully illuminated by X-ray crystallography. The steric environment of these chiral ruthenium complexes 4b-d was evaluated in asymmetric transfer hydrogenation (ATH) of prochiral ketones in the presence of (NaOPr)-Pr-i by using 2-propanol as the hydrogen source and solvent. The resultant catalytic system can achieve very good enantioselectivities (up to 91%) and high yields (up to 99%). (C) 2015 Elsevier B.V. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/59253</dc:identifier>
  <dc:identifier>oai:zenodo.org:59253</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>CATALYSIS COMMUNICATIONS 74 122-125</dc:source>
  <dc:title>Asymmetric transfer hydrogenation of ketones by N,N-containing quinazoline-based ruthenium(II) complexes</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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