1 Ocak 2016 Dergi makalesi Açık Erişim

Kucukturkmen, Cigdem; Agac, Ahmet; Eren, Aysel; Karakaya, Idris; Aslantas, Mehmet; Celik, Omer; Ulukanli, Sabri; Karabuga, Semistan

JSON-LD (schema.org)

{
  "@context": "https://schema.org/", 
  "@id": 59253, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Kilis 7 Aralik Univ, Fac Sci & Letters, Dept Chem, TR-79100 Kilis, Turkey", 
      "name": "Kucukturkmen, Cigdem"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey", 
      "name": "Agac, Ahmet"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey", 
      "name": "Eren, Aysel"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Osmaniye Korkut Ata Univ, Fac Sci & Letters, Dept Chem, TR-80000 Osmaniye, Turkey", 
      "name": "Karakaya, Idris"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey", 
      "name": "Aslantas, Mehmet"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Dicle Univ, Fac Sci & Letters, Dept Chem, TR-21280 Diyarbakir, Turkey", 
      "name": "Celik, Omer"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Osmaniye Korkut Ata Univ, Fac Sci & Letters, Dept Chem, TR-80000 Osmaniye, Turkey", 
      "name": "Ulukanli, Sabri"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey", 
      "name": "Karabuga, Semistan"
    }
  ], 
  "datePublished": "2016-01-01", 
  "description": "The novel set of quinazoline-based chiral ligands was synthesized starting from optically pure amino acids. Coordination with RuCl2(PPh3)dppb gave ruthenium(II) N-heterocyclic complexes 4b-d. The structure of complex 4b was fully illuminated by X-ray crystallography. The steric environment of these chiral ruthenium complexes 4b-d was evaluated in asymmetric transfer hydrogenation (ATH) of prochiral ketones in the presence of (NaOPr)-Pr-i by using 2-propanol as the hydrogen source and solvent. The resultant catalytic system can achieve very good enantioselectivities (up to 91%) and high yields (up to 99%). (C) 2015 Elsevier B.V. All rights reserved.", 
  "headline": "Asymmetric transfer hydrogenation of ketones by N,N-containing quinazoline-based ruthenium(II) complexes", 
  "identifier": 59253, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Asymmetric transfer hydrogenation of ketones by N,N-containing quinazoline-based ruthenium(II) complexes", 
  "url": "https://aperta.ulakbim.gov.tr/record/59253"
}