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Asymmetric transfer hydrogenation of ketones by N,N-containing quinazoline-based ruthenium(II) complexes

Kucukturkmen, Cigdem; Agac, Ahmet; Eren, Aysel; Karakaya, Idris; Aslantas, Mehmet; Celik, Omer; Ulukanli, Sabri; Karabuga, Semistan


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        "affiliation": "Kilis 7 Aralik Univ, Fac Sci & Letters, Dept Chem, TR-79100 Kilis, Turkey", 
        "name": "Kucukturkmen, Cigdem"
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        "affiliation": "Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey", 
        "name": "Agac, Ahmet"
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      {
        "affiliation": "Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey", 
        "name": "Eren, Aysel"
      }, 
      {
        "affiliation": "Osmaniye Korkut Ata Univ, Fac Sci & Letters, Dept Chem, TR-80000 Osmaniye, Turkey", 
        "name": "Karakaya, Idris"
      }, 
      {
        "affiliation": "Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey", 
        "name": "Aslantas, Mehmet"
      }, 
      {
        "affiliation": "Dicle Univ, Fac Sci & Letters, Dept Chem, TR-21280 Diyarbakir, Turkey", 
        "name": "Celik, Omer"
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      {
        "affiliation": "Osmaniye Korkut Ata Univ, Fac Sci & Letters, Dept Chem, TR-80000 Osmaniye, Turkey", 
        "name": "Ulukanli, Sabri"
      }, 
      {
        "affiliation": "Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey", 
        "name": "Karabuga, Semistan"
      }
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    "description": "The novel set of quinazoline-based chiral ligands was synthesized starting from optically pure amino acids. Coordination with RuCl2(PPh3)dppb gave ruthenium(II) N-heterocyclic complexes 4b-d. The structure of complex 4b was fully illuminated by X-ray crystallography. The steric environment of these chiral ruthenium complexes 4b-d was evaluated in asymmetric transfer hydrogenation (ATH) of prochiral ketones in the presence of (NaOPr)-Pr-i by using 2-propanol as the hydrogen source and solvent. The resultant catalytic system can achieve very good enantioselectivities (up to 91%) and high yields (up to 99%). (C) 2015 Elsevier B.V. All rights reserved.", 
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      "pages": "122-125", 
      "title": "CATALYSIS COMMUNICATIONS", 
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    "title": "Asymmetric transfer hydrogenation of ketones by N,N-containing quinazoline-based ruthenium(II) complexes"
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