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[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule

Ustun, E.; Dusunceli, S. Demir; Ozdemir, I.


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{
  "@context": "https://schema.org/", 
  "@id": 52649, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Ordu Univ, Fac Art & Sci, Dept Chem, TR-52200 Ordu, Turkey", 
      "name": "Ustun, E."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Inonu Univ, Dept Chem, Fac Sci, TR-44280 Malatya, Turkey", 
      "name": "Dusunceli, S. Demir"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Inonu Univ, Dept Chem, Fac Sci, TR-44280 Malatya, Turkey", 
      "name": "Ozdemir, I."
    }
  ], 
  "datePublished": "2017-01-01", 
  "description": "Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program.", 
  "headline": "[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule", 
  "identifier": 52649, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule", 
  "url": "https://aperta.ulakbim.gov.tr/record/52649"
}
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