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[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule

Ustun, E.; Dusunceli, S. Demir; Ozdemir, I.


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{
  "URL": "https://aperta.ulakbim.gov.tr/record/52649", 
  "abstract": "Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program.", 
  "author": [
    {
      "family": "Ustun", 
      "given": " E."
    }, 
    {
      "family": "Dusunceli", 
      "given": " S. Demir"
    }, 
    {
      "family": "Ozdemir", 
      "given": " I."
    }
  ], 
  "container_title": "BULGARIAN CHEMICAL COMMUNICATIONS", 
  "id": "52649", 
  "issued": {
    "date-parts": [
      [
        2017, 
        1, 
        1
      ]
    ]
  }, 
  "page": "50-56", 
  "title": "[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule", 
  "type": "article-journal", 
  "volume": "49"
}
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