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Ustun, E.; Dusunceli, S. Demir; Ozdemir, I.
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/52649</identifier> <creators> <creator> <creatorName>Ustun, E.</creatorName> <givenName>E.</givenName> <familyName>Ustun</familyName> <affiliation>Ordu Univ, Fac Art & Sci, Dept Chem, TR-52200 Ordu, Turkey</affiliation> </creator> <creator> <creatorName>Dusunceli, S. Demir</creatorName> <givenName>S. Demir</givenName> <familyName>Dusunceli</familyName> <affiliation>Inonu Univ, Dept Chem, Fac Sci, TR-44280 Malatya, Turkey</affiliation> </creator> <creator> <creatorName>Ozdemir, I.</creatorName> <givenName>I.</givenName> <familyName>Ozdemir</familyName> <affiliation>Inonu Univ, Dept Chem, Fac Sci, TR-44280 Malatya, Turkey</affiliation> </creator> </creators> <titles> <title>[Mn(Co)(3)(Bpy)(N-2-Chlorobenzylbenzimidazole)] Otf Complex As A New Photoactivatable Co-Releasing Molecule</title> </titles> <publisher>Aperta</publisher> <publicationYear>2017</publicationYear> <dates> <date dateType="Issued">2017-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/52649</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.81043/aperta.52648</relatedIdentifier> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.81043/aperta.52649</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract">Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program.</description> </descriptions> </resource>
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