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[Mn(CO)(3)(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule

Ustun, E.; Dusunceli, S. Demir; Ozdemir, I.


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/52649</identifier>
  <creators>
    <creator>
      <creatorName>Ustun, E.</creatorName>
      <givenName>E.</givenName>
      <familyName>Ustun</familyName>
      <affiliation>Ordu Univ, Fac Art &amp; Sci, Dept Chem, TR-52200 Ordu, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Dusunceli, S. Demir</creatorName>
      <givenName>S. Demir</givenName>
      <familyName>Dusunceli</familyName>
      <affiliation>Inonu Univ, Dept Chem, Fac Sci, TR-44280 Malatya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ozdemir, I.</creatorName>
      <givenName>I.</givenName>
      <familyName>Ozdemir</familyName>
      <affiliation>Inonu Univ, Dept Chem, Fac Sci, TR-44280 Malatya, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>[Mn(Co)(3)(Bpy)(N-2-Chlorobenzylbenzimidazole)] Otf Complex As A New Photoactivatable Co-Releasing Molecule</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2017</publicationYear>
  <dates>
    <date dateType="Issued">2017-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/52649</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsVersionOf">10.81043/aperta.52648</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.81043/aperta.52649</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program.</description>
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