1 Ocak 2017 Dergi makalesi Açık Erişim

Incel, Anil; Emirdag-Eanes, Mehtap; McMillen, Colin D.; Demir, Mustafa M.

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        "affiliation": "Izmir Inst Technol, Dept Mat Sci & Engn, TR-35430 Izmir, Turkey", 
        "name": "Incel, Anil"
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      {
        "affiliation": "Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkey", 
        "name": "Emirdag-Eanes, Mehtap"
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      {
        "affiliation": "Clemson Univ, Dept Chem, 219 Hunter Labs, Clemson, SC 29634 USA", 
        "name": "McMillen, Colin D."
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      {
        "affiliation": "Izmir Inst Technol, Dept Mat Sci & Engn, TR-35430 Izmir, Turkey", 
        "name": "Demir, Mustafa M."
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    "description": "Lanthanide-based organometallic materials are well-known candidate triboluminescent (TL) materials that can show bright emission when a mechanical force is applied. These materials are usually in the form of crystalline powders, and it is often useful to integrate these samples into a polymer matrix in order to achieve processability, enabling coating from a solution/molten state or fabrication as a complex-shaped matrix. In this work, micrometer-sized europium tetrakis (dibenzoylmethide) triethylammonium (EuD(4)TEA) crystals were synthesized and integrated with various transparent polymers (PMMA, PS, PVDF, and PU) using two approaches: (0 blending and (ii) surface impregnation. In the former method, the crystalline particles were molecularly dissolved; therefore, a TL response cannot be achieved. More than 10 wt % TL crystals in the composite is needed to obtain TL signals. However, TL signal was achieved at 2.5 wt % when a composite was prepared by the latter approach. TL intensity shows exponential decay with consecutive mechanical action. The TL emission of PU-based surface impregnated composite expires with long-lived emission, and maximum TL response with respect to applied force was measured between 2.45 and 42.0 N.", 
    "doi": "10.1021/acsami.6b16330", 
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      "issue": "7", 
      "pages": "6488-6496", 
      "title": "ACS APPLIED MATERIALS & INTERFACES", 
      "volume": "9"
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    "publication_date": "2017-01-01", 
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    "title": "Integration of Triboluminescent EuD(4)TEA Crystals to Transparent Polymers: Impact Sensor Application"
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