1 Ocak 2017 Dergi makalesi Açık Erişim

Incel, Anil; Emirdag-Eanes, Mehtap; McMillen, Colin D.; Demir, Mustafa M.

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/50377</identifier>
  <creators>
    <creator>
      <creatorName>Incel, Anil</creatorName>
      <givenName>Anil</givenName>
      <familyName>Incel</familyName>
      <affiliation>Izmir Inst Technol, Dept Mat Sci &amp; Engn, TR-35430 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Emirdag-Eanes, Mehtap</creatorName>
      <givenName>Mehtap</givenName>
      <familyName>Emirdag-Eanes</familyName>
      <affiliation>Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>McMillen, Colin D.</creatorName>
      <givenName>Colin D.</givenName>
      <familyName>McMillen</familyName>
      <affiliation>Clemson Univ, Dept Chem, 219 Hunter Labs, Clemson, SC 29634 USA</affiliation>
    </creator>
    <creator>
      <creatorName>Demir, Mustafa M.</creatorName>
      <givenName>Mustafa M.</givenName>
      <familyName>Demir</familyName>
      <affiliation>Izmir Inst Technol, Dept Mat Sci &amp; Engn, TR-35430 Izmir, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Integration Of Triboluminescent Eud(4)Tea Crystals To Transparent Polymers: Impact Sensor Application</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2017</publicationYear>
  <dates>
    <date dateType="Issued">2017-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/50377</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1021/acsami.6b16330</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Lanthanide-based organometallic materials are well-known candidate triboluminescent (TL) materials that can show bright emission when a mechanical force is applied. These materials are usually in the form of crystalline powders, and it is often useful to integrate these samples into a polymer matrix in order to achieve processability, enabling coating from a solution/molten state or fabrication as a complex-shaped matrix. In this work, micrometer-sized europium tetrakis (dibenzoylmethide) triethylammonium (EuD(4)TEA) crystals were synthesized and integrated with various transparent polymers (PMMA, PS, PVDF, and PU) using two approaches: (0 blending and (ii) surface impregnation. In the former method, the crystalline particles were molecularly dissolved; therefore, a TL response cannot be achieved. More than 10 wt % TL crystals in the composite is needed to obtain TL signals. However, TL signal was achieved at 2.5 wt % when a composite was prepared by the latter approach. TL intensity shows exponential decay with consecutive mechanical action. The TL emission of PU-based surface impregnated composite expires with long-lived emission, and maximum TL response with respect to applied force was measured between 2.45 and 42.0 N.</description>
  </descriptions>
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