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Self-assembly of organocatalysts for the enantioselective Michael addition of aldehydes to nitroalkenes

Demir, Ayhan S.; Eymur, Serkan


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{
  "@context": "https://schema.org/", 
  "@id": 28275, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey", 
      "name": "Demir, Ayhan S."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey", 
      "name": "Eymur, Serkan"
    }
  ], 
  "datePublished": "2010-01-01", 
  "description": "A proline-thiourea self-assembled organocatalyst is described as a good catalyst for the enantioselective nitro-Michael addition of aldehydes to nitroalkenes The reaction is efficient with 5% of the thiourea, to give moderate to good enantioselectivity (up to 76% ee) High syn-selectivity was obtained with both branched and unbranched aliphatic aldehydes This is the first example of self-assembly of organocatalysts with an achiral additive in a Michael addition wherein aldehydes are utilized as donors. (c) 2009 Elsevier Ltd All rights reserved", 
  "headline": "Self-assembly of organocatalysts for the enantioselective Michael addition of aldehydes to nitroalkenes", 
  "identifier": 28275, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Self-assembly of organocatalysts for the enantioselective Michael addition of aldehydes to nitroalkenes", 
  "url": "https://aperta.ulakbim.gov.tr/record/28275"
}
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