Dergi makalesi Açık Erişim
Demir, Ayhan S.; Eymur, Serkan
{ "@context": "https://schema.org/", "@id": 28275, "@type": "ScholarlyArticle", "creator": [ { "@type": "Person", "affiliation": "Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey", "name": "Demir, Ayhan S." }, { "@type": "Person", "affiliation": "Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey", "name": "Eymur, Serkan" } ], "datePublished": "2010-01-01", "description": "A proline-thiourea self-assembled organocatalyst is described as a good catalyst for the enantioselective nitro-Michael addition of aldehydes to nitroalkenes The reaction is efficient with 5% of the thiourea, to give moderate to good enantioselectivity (up to 76% ee) High syn-selectivity was obtained with both branched and unbranched aliphatic aldehydes This is the first example of self-assembly of organocatalysts with an achiral additive in a Michael addition wherein aldehydes are utilized as donors. (c) 2009 Elsevier Ltd All rights reserved", "headline": "Self-assembly of organocatalysts for the enantioselective Michael addition of aldehydes to nitroalkenes", "identifier": 28275, "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", "license": "http://www.opendefinition.org/licenses/cc-by", "name": "Self-assembly of organocatalysts for the enantioselective Michael addition of aldehydes to nitroalkenes", "url": "https://aperta.ulakbim.gov.tr/record/28275" }
Görüntülenme | 27 |
İndirme | 7 |
Veri hacmi | 1.2 kB |
Tekil görüntülenme | 26 |
Tekil indirme | 6 |