1 Ocak 2023 Dergi makalesi Açık Erişim

Dilek, Omer; Erturk, Erkan

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{
  "@context": "https://schema.org/", 
  "@id": 265264, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Dilek, Omer"
    }, 
    {
      "@type": "Person", 
      "affiliation": "TUBITAK Marmara Res Ctr, TR-41470 Gebze, Kocaeli, Turkiye", 
      "name": "Erturk, Erkan"
    }
  ], 
  "datePublished": "2023-01-01", 
  "description": "<p>Enantioselective reduction of a new 1-oxotetrahydrocarbazole compound (ethyl 2-(1-oxo-9-tosyl-2,3,4,9-tetrahydro-1H-carbazol-2-yl)acetate) through asymmetric transfer hydrogenation by using the commercially available Noyori-Ikariya ruthenium catalyst and HCO2H/Et3N or HCO2H/DABCO as the hydrogen source have been investigated. High enantiomeric excesses (up to 96% ee) and moderate to good yields (24-72%) for corresponding alcohol and lactone compounds have been achieved. Structures of all compounds have been characterized by spectroscopic techniques.</p>", 
  "headline": "Asymmetric transfer hydrogenation of a new N- tosyltetrahydrocarbazole-1-one ester with the Noyori-Ikariya catalyst", 
  "identifier": 265264, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Asymmetric transfer hydrogenation of a new N- tosyltetrahydrocarbazole-1-one ester with the Noyori-Ikariya catalyst", 
  "url": "https://aperta.ulakbim.gov.tr/record/265264"
}