Dergi makalesi Açık Erişim
Dilek, Omer; Erturk, Erkan
{
"conceptrecid": "265263",
"created": "2024-06-07T11:29:10.115596+00:00",
"doi": "10.25135/acg.oc2307.2838",
"files": [
{
"bucket": "53928006-30b2-4ecb-bcb0-7320da62c363",
"checksum": "md5:b9aa42a0b78dc8434968a3e98fa3f257",
"key": "10-25135-acg-oc2307-2838.pdf",
"links": {
"self": "https://aperta.ulakbim.gov.tr/api/files/53928006-30b2-4ecb-bcb0-7320da62c363/10-25135-acg-oc2307-2838.pdf"
},
"size": 501311,
"type": "pdf"
}
],
"id": 265264,
"links": {
"badge": "https://aperta.ulakbim.gov.tr/badge/doi/10.25135/acg.oc2307.2838.svg",
"bucket": "https://aperta.ulakbim.gov.tr/api/files/53928006-30b2-4ecb-bcb0-7320da62c363",
"doi": "https://doi.org/10.25135/acg.oc2307.2838",
"html": "https://aperta.ulakbim.gov.tr/record/265264",
"latest": "https://aperta.ulakbim.gov.tr/api/records/265264",
"latest_html": "https://aperta.ulakbim.gov.tr/record/265264"
},
"metadata": {
"access_right": "open",
"access_right_category": "success",
"communities": [
{
"id": "tubitak-adresli-yayinlar"
}
],
"creators": [
{
"name": "Dilek, Omer"
},
{
"affiliation": "TUBITAK Marmara Res Ctr, TR-41470 Gebze, Kocaeli, Turkiye",
"name": "Erturk, Erkan"
}
],
"description": "<p>Enantioselective reduction of a new 1-oxotetrahydrocarbazole compound (ethyl 2-(1-oxo-9-tosyl-2,3,4,9-tetrahydro-1H-carbazol-2-yl)acetate) through asymmetric transfer hydrogenation by using the commercially available Noyori-Ikariya ruthenium catalyst and HCO2H/Et3N or HCO2H/DABCO as the hydrogen source have been investigated. High enantiomeric excesses (up to 96% ee) and moderate to good yields (24-72%) for corresponding alcohol and lactone compounds have been achieved. Structures of all compounds have been characterized by spectroscopic techniques.</p>",
"doi": "10.25135/acg.oc2307.2838",
"has_grant": false,
"journal": {
"issue": "3",
"pages": "8",
"title": "ORGANIC COMMUNICATIONS",
"volume": "16"
},
"license": {
"id": "cc-by"
},
"publication_date": "2023-01-01",
"relations": {
"version": [
{
"count": 1,
"index": 0,
"is_last": true,
"last_child": {
"pid_type": "recid",
"pid_value": "265264"
},
"parent": {
"pid_type": "recid",
"pid_value": "265263"
}
}
]
},
"resource_type": {
"subtype": "article",
"title": "Dergi makalesi",
"type": "publication"
},
"science_branches": [
"Di\u011fer"
],
"title": "Asymmetric transfer hydrogenation of a new N- tosyltetrahydrocarbazole-1-one ester with the Noyori-Ikariya catalyst"
},
"owners": [
1
],
"revision": 1,
"stats": {
"downloads": 14.0,
"unique_downloads": 14.0,
"unique_views": 70.0,
"version_downloads": 14.0,
"version_unique_downloads": 14.0,
"version_unique_views": 63.0,
"version_views": 67.0,
"version_volume": 7018354.0,
"views": 74.0,
"volume": 7018354.0
},
"updated": "2024-06-07T11:29:10.160090+00:00"
}
| Görüntülenme | 74 |
| İndirme | 14 |
| Veri hacmi | 7.0 MB |
| Tekil görüntülenme | 70 |
| Tekil indirme | 14 |