1 Ocak 2023 Dergi makalesi Açık Erişim

Dilek, Omer; Erturk, Erkan

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/265264</identifier>
  <creators>
    <creator>
      <creatorName>Dilek, Omer</creatorName>
      <givenName>Omer</givenName>
      <familyName>Dilek</familyName>
    </creator>
    <creator>
      <creatorName>Erturk, Erkan</creatorName>
      <givenName>Erkan</givenName>
      <familyName>Erturk</familyName>
      <affiliation>TUBITAK Marmara Res Ctr, TR-41470 Gebze, Kocaeli, Turkiye</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Asymmetric Transfer Hydrogenation Of A New N- Tosyltetrahydrocarbazole-1-One Ester With The Noyori-Ikariya Catalyst</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2023</publicationYear>
  <dates>
    <date dateType="Issued">2023-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/265264</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.25135/acg.oc2307.2838</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">&lt;p&gt;Enantioselective reduction of a new 1-oxotetrahydrocarbazole compound (ethyl 2-(1-oxo-9-tosyl-2,3,4,9-tetrahydro-1H-carbazol-2-yl)acetate) through asymmetric transfer hydrogenation by using the commercially available Noyori-Ikariya ruthenium catalyst and HCO2H/Et3N or HCO2H/DABCO as the hydrogen source have been investigated. High enantiomeric excesses (up to 96% ee) and moderate to good yields (24-72%) for corresponding alcohol and lactone compounds have been achieved. Structures of all compounds have been characterized by spectroscopic techniques.&lt;/p&gt;</description>
  </descriptions>
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