1 Ocak 2010 Dergi makalesi Açık Erişim

Guney, Emel; Yilmaz, Veysel T.; Sengul, Abdurrahman; Buyukgungor, Orhan

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  <dc:creator>Guney, Emel</dc:creator>
  <dc:creator>Yilmaz, Veysel T.</dc:creator>
  <dc:creator>Sengul, Abdurrahman</dc:creator>
  <dc:creator>Buyukgungor, Orhan</dc:creator>
  <dc:date>2010-01-01</dc:date>
  <dc:description>[Pd(sac)(terpy)](sac)center dot 4H(2)O (1), [Pt(sac)(terpy)](sac)center dot 5H(2)O (2), [PdCl(terpy)](sac)center dot 2H(2)O (3) and [PtCl(terpy)](sac)center dot 2H(2)O (4) (sac = saccharinate, and terpy = 2,2': 6',2 ''-terpyridine) have been synthesized and characterized by elemental analysis, FT-IR, H-1 NMR and C-13 NMR. In 1 and 2, a tridentate terpy ligand together with an N-coordinated sac ligand form the square-planar geometry around the palladium(II) or platinum(II) ions, while one sac anion remains outside the coordination sphere as a counter-ion. Xray single crystal studies show that the [M(sac)(terpy)](+) ions in 1 and 2 reside in the centers of a hydrogen bonded honeycomb network formed by the uncoordinated sac ions and the lattice water molecules. Complexes 3 and 4 are isostructural and consist of a [M(Cl)(terpy)](+) cation, a sac anion and two lattice water molecules. The [M(Cl)(terpy)](+) ions interact with each other via M-M and pi-pi stacking interactions and these p interacted units are assembled to a 2D network by water bridges involving the sac ions and lattice water molecules. Convenient synthetic paths for 1-4 are also presented, and spectral, luminescence and thermal properties were discussed. (C) 2009 Elsevier B. V. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/25939</dc:identifier>
  <dc:identifier>oai:zenodo.org:25939</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>INORGANICA CHIMICA ACTA 363(2) 438-448</dc:source>
  <dc:title>Platinum(II) and palladium(II) saccharinato complexes with 2,2 ':6 ',2 ''-terpyridine: Synthesis, characterization, crystal structures, photoluminescence and thermal studies</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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